Lithium ion batteries (LIB) are considered as prime candidates for electric vehicles. Among them, batteries with silicon nanoparticles (SiNPs) based negative electrode are very promising, thanks to their important energy storage capacity, ten times higher than the current ones. But their low cycling performance due to SiNPs degradation precludes further final applications. In this context, a breakthrough was recently achieved by researchers t our laboratory and IMN Nantes.